PUNK! Met Gala 2013 Red Carpet Gallery (PHOTOS)Isabel Wilkinson05.06.13PUNK! Met Gala 2013 Red Carpet Gallery (PHOTOS)The Costume Institute Gala honored the new ‘PUNK: Chaos to Couture’ exhibition. From Anna Wintour to Rooney Mara, see highlights from the red carpet. Isabel Wilkinson05.06.13 11:45 PM ETGetty The Costume Institute Gala honored the new PUNK: Chaos to Couture exhibition. From Anna Wintour to Rooney Mara, see highlights from the red carpet. Charles Sykes//Invision/APBeyoncéBeyoncé, the evening's co-chair (who arrived fashionably late) stole the show in a Givenchy Haute Couture by Riccardo Tisci long black skirt with flame motifs worn with matching printed cady thigh-high boots and high gloves, python leather corset, and python belt with gold eyelets. Dimitrios Kambouris/GettyAnne Hathaway A newly blonde Anne Hathaway wore a black vintage Valentino dress from 1992. Larry BusaccaJennifer LawrenceThe Hunger Games actress, who attended with designer Raf Simons, looked stunning in a black strapless Dior dress with a veil. Dimitrios Kambouris/GettyGwyneth PaltrowThe statuesque actress wore a bright pink Valentino dress with a cutout around the shoulders and Wilfredo Rosado earrings. "How is it punk? I guess it's pink!" she said of her dress. "We were wearing safety pins in the ears with our little Spence uniforms," she joked of remembering punk as she grew up in New York. Timothy A. Clary/AFP/GettyMadonna A late arrival, Madonna looked fierce in a black and gray tartan jacket embroidered with silver metal studs and safety pins —and no pants!—also by Givenchy Haute Couture by Riccardo Tisci. She offset the look with Casadei pink suede pumps. Kevin Mazur/WireImageRooney Mara and Riccardo TisciLongtime friend of Givenchy, Rooney Mara attended with the house's creative director, Riccardo Tisci—who is co-hosting the event—in a white Givenchy Haute Couture by Riccardo Tisci custom dress and Jennifer Meyer rings. “I don't think I had a punk fashion phase, but I was definitely a punk," she said. Said Tisci of Mara's dress: "I delivevered something that belonged with her skin, which was lace with a little metal. Dimitrios Kambouris/GettyKerry WashingtonWashington wore a purple metallic dress by Vera Wang, which she matched with purple streaks in her hair. "I think I may have discovered something new tonight," she said of her new hair. Dimitrios KambourisKristen StewartStewart, a punk by nature, wore a crimson lace jumpsuit by Stella McCartney. GettySarah Jessica ParkerThe actress took the cake with a Philip Treacy mohawk headpiece, Gilles dress, Fred Leighton jewels, and Christian Louboutin custom boots. "I wanted to pay attention to the theme," she said. Timothy A. Clary/AFP/GettyKanye West and Kim KardashianA very pregnant Kim Kardashian wore a floral turtleneck dress by Riccardo Tisci for Givenchy—complete with gloves attached. "I love fashion, and I'm really excited to see everyone's take on punk," she said. Her boyfriend, Kanye West, also wore a complete look by Tisci. Dimitrios Kambouris/GettyLena Dunham and Erdem MoraliogluThe Girls actress wore Erdem custom dress and shoes. "I'm wearing Erdem, and that's Erdem. I'm wearing him," Dunham said. Kevin Mazur/GettyGinnifer Goodwin Goodwin glittered in a Tory Burch custom gown embroidered metal palettes with black leather straps and strong black makeup on her eyebrows. Larry Busacca/GettyCarey MulliganThe Great Gatsby star looked minimal in a black Balenciaga dress, which she paired with Tiffany emerald earrings (valued at $165,000), a Tiffany square emerald-cut diamond ring with diamond surround set in platinum ($800,000), and a Tiffany bracelet in platinum with three rows of emerald-cut diamonds ($375,000). Dimitrios Kambouris/GettyNicki MinajThe blonde, curly haired rapper looked demure in a navy blue Tommy Hilfiger dress with cutouts. Dimitrios Kambouris/GettyBlake LivelyThe actress looked stunning in a Gucci Première pale green silk georgette strapless gown and Lorraine Schwartz jewels. Dimitrios Kambouris/GettyJessica Biel Jessica Biel layered up in a Giambattista Valli Haute Couture gown and pants of black macramé and tulle. Charles Sykes/Invision/APJennifer LopezJennifer Lopez was surprisingly covered up in a custom black leopard sequin-embroidered gown by Michael Kors. Dimitrios Kambouris/GettyMarc Jacobs (with Sophia Coppola)Jacobs wore a punk polka-dot Comme des Garçons suit. "I was going to wear a tuxedo, which I thought would be the most subversive thing to wear for punk," he said. Coppola wore a purple metallic Marc Jacobs pajama set. "I picked out these pajamas because they seemed comfortable and I didn't want to wear a gown," she said. Kevin MazurSienna MillerSienna Miller looked chic in a white column dress and studded cropped biker jacket, clutch and shoes (all by Burberry) and a Genevieve Jones white-gold ear cuff.